The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis
Résumé
The popularity of NHCs in transition metal catalysis has prompted the development of chiral versions as electron-rich neutral stereodirecting ancillary ligands for enantioselective transformations. Herein we demonstrate that cyclic (alkyl)(amino)carbene (CAAC) ligands can also engage in asymmetric transformations, thereby expanding the toolbox of available chiral carbenes.
Domaines
Chimie| Origine | Fichiers éditeurs autorisés sur une archive ouverte |
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