On the chemical condensation of the layers of zeolite precursor MCM-22(P)

Chemical condensation of layers of silicates has been often proposed as an alternative to thermal condensation, finding limited success. The formation of the industrially relevant MCM-22 zeolite (MWW IZA code) from a mild hydrothermal precursor is the most important example of 2D-3D aluminosilicate condensation. Silanols of opposed layers have been condensed by acid-driven dehydration in concentrated nitric acid, as confirmed by powder XRD and 29Si NMR spectroscopy, implying interlayer template extraction and corresponding dealumination. Milder acid treatments favour template extraction and shrinkage of interlayer distance, but do not provide significant silanol condensation. Template extraction is further favoured by degradation of the organics in the presence of a Cu2+ homogeneous catalyst.

Mots clés

Zeolite Layered material Acid condensation Template extraction Dealumination

Domaines

Chimie

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https://hal.umontpellier.fr/hal-03621696

Soumis le : jeudi 16 juin 2022-10:41:51

Dernière modification le : jeudi 7 novembre 2024-16:14:04

Dates et versions

hal-03621696 , version 1 (16-06-2022)

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Paternité - Pas d'utilisation commerciale - Pas de modification

Identifiants

HAL Id : hal-03621696 , version 1
DOI : 10.1016/j.micromeso.2021.111678

Citer

Marco Fabbiani, Amine Morsli, Giorgia Confalonieri, Thomas Cacciaguerra, François Fajula, et al.. On the chemical condensation of the layers of zeolite precursor MCM-22(P). Microporous and Mesoporous Materials, 2022, 332, pp.111678. ⟨10.1016/j.micromeso.2021.111678⟩. ⟨hal-03621696⟩

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