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Article Dans Une Revue European Journal of Organic Chemistry Année : 2002

Synthesis of a Linear Assembly Consisting of a Central Ru(Phen)32+ Derivative and Two Peripheral Porphyrins

Jean-Claude Chambron
Christine Goze
  • Fonction : Auteur
Valérie Heitz
Jean-Pierre Sauvage
  • Fonction : Auteur
Gilles Hanquet
  • Fonction : Auteur
Xavier J Salom-Roig
Sonia Lemeitour
  • Fonction : Auteur
Guy Solladié
  • Fonction : Auteur

Résumé

2-(2-Tetrahydrofurylidene)propionates, usually obtained only in the more stable (E) configuration 1, were efficiently isomerised into their (Z) isomers 2 by use of Lewis acids or metallated bases. The (E)/(Z) isomerisation was governed by different factors (type of chelating agent, nature and steric demand of the α,β-unsaturated group). We demonstrated that judicious selection of the α,β-unsaturated group, in combina

Domaines

Chimie organique

Dates et versions

hal-03468853 , version 1 (08-12-2021)

Identifiants

Citer

Xavier j. Salom-Roig, Jean-Claude Chambron, Christine Goze, Valérie Heitz, Jean-Pierre Sauvage, et al.. Synthesis of a Linear Assembly Consisting of a Central Ru(Phen)32+ Derivative and Two Peripheral Porphyrins. European Journal of Organic Chemistry, 2002, 2002 (19), pp.3276-3280. ⟨10.1002/1099-0690(200210)2002:19<3276::AID-EJOC3276>3.0.CO;2-R⟩. ⟨hal-03468853⟩
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