Preparation of Substituted Hydroquinones and Benzofurans from 1,4-Quinone Monoketals - Université de Montpellier
Article Dans Une Revue Synthesis: Journal of Synthetic Organic Chemistry Année : 2006

Preparation of Substituted Hydroquinones and Benzofurans from 1,4-Quinone Monoketals

Résumé

An easy procedure for the preparation of 2-substituted hydroquinones, by addition of organolithium or organomagnesium compounds to 1,4-quinone monoketals followed by acid-catalyzed dienone-phenol type rearrangement, is described. Transformation of the propargylated derivatives to benzofurans is also reported.

Domaines

Chimie organique
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Dates et versions

hal-03468809 , version 1 (08-12-2021)

Identifiants

Citer

Xavier J Salom-Roig, Philippe Renaud. Preparation of Substituted Hydroquinones and Benzofurans from 1,4-Quinone Monoketals. Synthesis: Journal of Synthetic Organic Chemistry, 2006, 2006 (20), pp.3419-3424. ⟨10.1055/s-2006-950236⟩. ⟨hal-03468809⟩
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