New TBT based conducting polymers functionalized with redox-active tetrazines

We describe the synthesis of two new polymerizable monomers, and the subsequent polymers functionalized by tetrazine pendant groups, along with their electrochemical behaviour and fluorescence properties. In all cases a very stable conducting polymer is obtained, featuring both the redox activity of the main chain in oxidation and of the tetrazine functional group upon reduction. One of the polymers in addition exhibits an electrofluorochromic behaviour.

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Chimie

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S1572665719301900.pdf (1.01 Mo)

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https://hal.umontpellier.fr/hal-02152645

Soumis le : vendredi 22 octobre 2021-16:45:33

Dernière modification le : jeudi 11 avril 2024-13:08:12

Archivage à long terme le : lundi 24 janvier 2022-16:59:23

Dates et versions

hal-02152645 , version 1 (22-10-2021)

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Paternité - Pas d'utilisation commerciale

Identifiants

HAL Id : hal-02152645 , version 1
DOI : 10.1016/j.jelechem.2019.03.029
PII : S1572-6657(19)30190-0

Citer

Laetitia Guerret-Legras, Pierre Audebert, Jean-Frédéric Audibert, Claude Niebel, Thibaut Jarrosson, et al.. New TBT based conducting polymers functionalized with redox-active tetrazines. Journal of Electroanalytical Chemistry, 2019, 840, pp.60-66. ⟨10.1016/j.jelechem.2019.03.029⟩. ⟨hal-02152645⟩

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