First observation of [Pu6(OH)4O4 ]12+ cluster during the hydrolytic formation of PuO2 nanoparticles using H/D kinetic isotope effect
Résumé
New insights are provided about the formation mechanism of PuO2 nanoparticles (NPs) by investigating an unprecedented kinetic isotope effect observed during their hydrolytic synthesis in H2O or D2O media.
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