 |
Article dans une revue
A platinum nanowire electrocatalyst on single-walled carbon nanotubes to drive hydrogen evolution
Abstract : Pertinent existing hydrogen technologies for energy storage require unsustainable amounts of scarce platinum group metals. Here, an electrocatalyst comprising high-aspect-ratio platinum nanowires (PtNWs) on single-walled carbon nanotubes (SWNTs) with ultralow Pt content (340 ng Pt cm −2) is employed for hydrogen evolution reaction (HER). A comparable activity (10 mA cm −2 at −18 mV vs. RHE) to that of state-of-the-art Pt/C (38,000 ng Pt cm −2) is reached in acidic aqueous electrolyte. This is attributed to favorable PtNW interaction with SWNTs and PtNW edge-sites which adsorb hydrogen optimally and aid at alleviating repulsive interactions. Moreover, the metallic nature of Pt, morphological effects and enhanced wetting contribute positively. The PtNW/SWNT relevance is emphasized at a proton-exchange-membrane electrolyzer generating stable voltage for more than 2000 h, successfully competing with the state-of-the-art reference but with one tenth of Pt mass loading. Overall, this work presents an unprecedently efficient HER catalyst and opens up avenues for PtNW/SWNT catalyzing other high-impact reactions.
https://hal.umontpellier.fr/hal-02519429
Contributeur : Icg Aigle Connectez-vous pour contacter le contributeur
Soumis le : mardi 17 novembre 2020 - 10:41:20
Dernière modification le : lundi 11 octobre 2021 - 13:23:21
Archivage à long terme le : : jeudi 18 février 2021 - 18:59:47
Contributeur : Icg Aigle Connectez-vous pour contacter le contributeur
Soumis le : mardi 17 novembre 2020 - 10:41:20
Dernière modification le : lundi 11 octobre 2021 - 13:23:21
Archivage à long terme le : : jeudi 18 février 2021 - 18:59:47
Fichier
1-s2.0-S0926337319313281-main ...
Publication financée par une institution
Licence
Distributed under a Creative Commons Paternité 4.0 International License