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Article Dans Une Revue Inorganic Chemistry Année : 2019

Synthesis, Characterization, and Functionalization of Tetrafunctional Double-Decker Siloxanes

Résumé

Novel tetravinyl- and tetraallyl-substituted closed double-decker siloxanes (DDSQs) were synthesized and characterized, and their structures were elucidated by X-ray crystallographic analysis. Moreover, it was shown that peripheral olefins could successfully undergo hydrosilylation quantitatively. Such tetrafunctionalizable DDSQs (DDSQ-Vinyl4 and DDSQ-Allyl4) thus constitute promising building blocks for more complex inorganic–organic hybrid materials. Synopsis Novel tetravinyl- and tetraallyl-substituted closed double-decker siloxanes (DDSQs) were synthesized and peripheral olefins shown to successfully undergo hydrosilylation quantitatively. Such tetrafunctionalizable DDSQs thus constitute promising building blocks for more complex inorganic−organic hybrid materials.
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Dates et versions

hal-02108359 , version 1 (11-12-2020)

Identifiants

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Yujia Liu, Nobuhiro Takeda, Armelle Ouali, Masafumi Unno. Synthesis, Characterization, and Functionalization of Tetrafunctional Double-Decker Siloxanes. Inorganic Chemistry, 2019, 58 (7), pp.4093-4098. ⟨10.1021/acs.inorgchem.9b00416⟩. ⟨hal-02108359⟩
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