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Mechanistic Insights into Dehydrogenation of Partially Deuterated Ammonia Borane NH 3 BD 3 Being Heating to 200 °C

Abstract : Ammonia borane NH3BH3 is a well-known thermolytic hydrogen storage material. However, the mechanism of dehydrogenation under heating is very complex. In this context, we have studied the thermolytic dehydrocoupling of solid, partially deuterated, ammonia borane NH3BD3 up to 200 degrees C, that is, up to the release of the second equivalent of hydrogen, by using thermogravimetric analysis, differential scanning calorimetry, and mass spectrometry. Our results show that the process, resulting in the release of hydrogen (i.e., HD), is mainly driven by heteropolar hydrogen-deuterium interactions (N-H delta+center dot center dot center dot D delta--B). Homopolar dihydrogen interactions (N-H delta+center dot center dot center dot H delta+-N) appreciably contribute to hydrogen (i.e., H-2) release. In contrast, the contribution of homopolar dideuterium interactions (B-D delta-center dot center dot center dot D delta--B) is negligible. In summary, this work sheds new light on the mechanism governing the release of hydrogen from ammonia borane under thermolytic conditions.
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https://hal.umontpellier.fr/hal-01996078
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Soumis le : lundi 28 janvier 2019 - 10:35:56
Dernière modification le : vendredi 5 août 2022 - 11:00:56

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Jean-Fabien Petit, Umit Demirci. Mechanistic Insights into Dehydrogenation of Partially Deuterated Ammonia Borane NH 3 BD 3 Being Heating to 200 °C. Inorganic Chemistry, American Chemical Society, 2018, 58 (1), pp.489-494. ⟨10.1021/acs.inorgchem.8b02721⟩. ⟨hal-01996078⟩

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