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Article Dans Une Revue Bioresource Technology Année : 2017

Modeling competitive sorption of lead and copper ions onto alginate and greenly prepared algal-based beads

Shengye Wang
  • Fonction : Auteur
Thierry Vincent
Catherine Faur
Eric Guibal

Résumé

The binary sorption of Pb(II) and Cu(II) onto calcium alginate, algal biomass and algal/glutaraldehyde-crosslinked polyethyleneimine (PEI) composite beads was studied in the absence and presence of Ca(II). Different competitive models were compared for predicting the equilibrium data. Results show that all the sorbents have a significant preference for Pb(II) over Cu(II) in Pb-Cu system: the separation factors reach 14.1, 9.1 and 3.6 for alginate, algal biomass and algal/PEI beads, respectively. Kinetic studies confirm the occurrence of an ion-exchange mechanism between Pb(II) and Cu(II) as the sorption sites are progressively saturated. Competitive Sips model predicts well the sorption data for all the sorbents. In Pb-Cu-Ca system, the Cu(II) sorption by algal beads was negligible, while algal/PEI still maintained a significant sorption of Cu(II) sorption under these conditions.
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Dates et versions

hal-01670196 , version 1 (21-12-2017)

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Citer

Shengye Wang, Thierry Vincent, Catherine Faur, Eric Guibal. Modeling competitive sorption of lead and copper ions onto alginate and greenly prepared algal-based beads. Bioresource Technology, 2017, 231, pp.26 - 35. ⟨10.1016/j.biortech.2017.01.066⟩. ⟨hal-01670196⟩
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