This paper presents the successful preparation of porous membranes based on chitosan with enhanced mechanical, thermal and chemical properties applicable in water treatment field. Herein, chitosan/kaolin composite membranes with a cross-linking agent and a porogen were prepared using the solvent casting method. The characterization of the as-fabricated membranes indicated that the combined effect of kaolin as reinforcing agent, polyethylene glycol as pore former and citric acid as cross-linker in a chitosan matrix showed a significant influence on the membrane properties. The results indicated that the incorporation of a hydrophilic porogenic reagent into the collodion in addition to providing a porous morphology makes it possible to obtain a more hydrophilic membrane, and thus induces an increase in the pure water permeability. The cross-linked membranes exhibited an improved water resistance, better thermal and mechanical properties as compared to neat chitosan films. The cross-linked membranes had a mean pore size of 50 nm falling in the range of ultrafiltration. Their functional properties were determined in terms of pure water filtration and molecular weight cut-off tests.