Facile modifications of HKUST-1 by V, Nb and Mn for low-temperature selective catalytic reduction of nitrogen oxides by NH 3 - Université de Montpellier Accéder directement au contenu
Article Dans Une Revue Catalysis Today Année : 2022

Facile modifications of HKUST-1 by V, Nb and Mn for low-temperature selective catalytic reduction of nitrogen oxides by NH 3

Résumé

HKUST-1 catalysts were impregnated with vanadium, niobium and manganese species and tested in NH 3-SCR for NO removal. No reduction of NO by NH 3 was registered for the unmodified HKUST-1 and disappearance of NO was attributed to adsorption. After a pretreatment at 185°C, the best catalytic performance was found for HKUST-1-Mn with 100% and 80% conversion of NH 3 and NO, respectively at 185°C. For the first time, the H 2 O tolerance was examined on the modified HKUST-1 catalyst. The addition of water vapor resulted in decrease of NO and NH 3 conversions, which was immediately recovered when H 2 O feeding was stopped. The NO conversion dropped from 76% to 68% after 35 min of H 2 O addition.

Domaines

Catalyse
Fichier principal
Vignette du fichier
CatToday HKUST.pdf (5.91 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-03517472 , version 1 (07-01-2022)

Identifiants

Citer

Katarzyna Świrk, Gérard Delahay, Abdelali Zaki, Karim Adil, Amandine Cadiau. Facile modifications of HKUST-1 by V, Nb and Mn for low-temperature selective catalytic reduction of nitrogen oxides by NH 3. Catalysis Today, 2022, 384-386, pp.25-32. ⟨10.1016/j.cattod.2021.07.017⟩. ⟨hal-03517472⟩
64 Consultations
74 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More