Metal-free mechanochemical oxidations in Ertalyte ® jars

Abstract : Aimed at eliminating or at least significantly reducing the use of solvents, sodium hypochlorite pentahydrate crystals (NaOCl·5H2O) in the presence of a catalytic amount of a nitrosyl radical (TEMPO or AZADO) have been successfully used to induce mechanochemical oxidative processes on several structurally different primary and secondary alcohols. The proposed redox process is safe, inexpensive and performing effectively, especially on the macroscale. Herein, an Ertalyte® jar has been successfully used, for the first time, in a mechanochemical process.
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https://hal.umontpellier.fr/hal-02279916
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Soumis le : jeudi 5 septembre 2019 - 16:13:47
Dernière modification le : vendredi 6 septembre 2019 - 01:21:44

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Andrea Porcheddu, Francesco Delogu, Lidia de Luca, Claudia Fattuoni, Evelina Colacino. Metal-free mechanochemical oxidations in Ertalyte ® jars. Beilstein Journal of Organic Chemistry, Beilstein-Institut, 2019, 15, pp.1786-1794. ⟨10.3762/bjoc.15.172⟩. ⟨hal-02279916⟩

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