In situ grazing incidence small-angle x-ray scattering real-time monitoring of the role of humidity during the structural formation of templated silica thin films - Université de Montpellier
Article Dans Une Revue Physical Review B: Condensed Matter and Materials Physics (1998-2015) Année : 2004

In situ grazing incidence small-angle x-ray scattering real-time monitoring of the role of humidity during the structural formation of templated silica thin films

Résumé

The role of RH (relative humidity) during the formation of templated silica thin films has been investigated using real-time grazing incidence small-angle x-ray scattering. A detailed analysis of the evolution of the lattice parameters as a function of RH is presented. It is shown that in the modulable steady state, the lattice parameter parallel to the surface is pinned after a transient regime is reached while the parameter normal to the surface can still vary. In the initial stage we find that the film can take up to one layer of water per micelle. Interferometric measurements confirm that swelling occurs in the entire film. An explanation of the pinning effect is presented.

Domaines

Chimie
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Dates et versions

hal-01999353 , version 1 (13-09-2024)

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Alain Gibaud, Sandrine Dourdain, Oleg Gang, Benjamin Ocko. In situ grazing incidence small-angle x-ray scattering real-time monitoring of the role of humidity during the structural formation of templated silica thin films. Physical Review B: Condensed Matter and Materials Physics (1998-2015), 2004, 70 (16), pp.161403. ⟨10.1103/PhysRevB.70.161403⟩. ⟨hal-01999353⟩
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