S. U. Khan, M. Shahry, W. B. Ingler, and . Jr, Efficient Photochemical Water Splitting by a Chemically Modified n-TiO2, Science, vol.297, issue.5590, pp.2243-2245, 2002.
DOI : 10.1126/science.1075035

Y. Ma, Titanium Dioxide-Based Nanomaterials for Photocatalytic Fuel Generations, Chemical Reviews, vol.114, issue.19, pp.9987-10043, 2014.
DOI : 10.1021/cr500008u

Y. Bai, I. Mora-sero, F. De-angelis, J. Bisquert, and P. Wang, Titanium Dioxide Nanomaterials for Photovoltaic Applications, Chemical Reviews, vol.114, issue.19, pp.10095-10130, 2014.
DOI : 10.1021/cr400606n

URL : http://repositori.uji.es/xmlui/bitstream/10234/127945/1/Registro_acceso_restringido%20%281%29.pdf

K. Onda, Wet Electrons at the H2O/TiO2(110) Surface, Science, vol.308, issue.5725, pp.1154-1158, 2005.
DOI : 10.1126/science.1109366

Y. He, A. Tilocca, O. Dulub, A. Selloni, and U. Diebold, Local ordering and electronic signatures of submonolayer water on anatase TiO2(101), Nature Materials, vol.31, issue.7, pp.585-589, 2009.
DOI : 10.1038/nmat2466

T. Rajh, N. M. Dimitrijevic, M. Bissonnette, T. Koritarov, and V. Konda, Titanium Dioxide in the Service of the Biomedical Revolution, Chemical Reviews, vol.114, issue.19, pp.10177-10216, 2014.
DOI : 10.1021/cr500029g

T. Froschl, High surface area crystalline titanium dioxide: potential and limits in electrochemical energy storage and catalysis, Chemical Society Reviews, vol.11, issue.10, pp.5313-5360, 2012.
DOI : 10.1002/cphc.200900769

S. M. Kuznicki, A titanosilicate molecular sieve with adjustable pores for size-selective adsorption of molecules, Nature, vol.51, issue.6848, pp.720-724, 2001.
DOI : 10.1016/0025-5408(88)90019-0

C. Serre, F. Taulelle, and G. Ferey, Rational design of porous titanophosphates, Chem. Commun, pp.2755-2765, 2003.
DOI : 10.1002/chin.200403241

H. C. Zhou and S. Kitagawa, Metal???Organic Frameworks (MOFs), Chem. Soc. Rev., vol.43, issue.16, pp.5415-5418, 2014.
DOI : 10.1039/C4CS90059F

H. C. Zhou, J. R. Long, and O. M. Yaghi, Introduction to Metal???Organic Frameworks, Chemical Reviews, vol.112, issue.2, pp.673-674, 2012.
DOI : 10.1021/cr300014x

G. Maurin, C. Serre, A. Cooper, and G. Ferey, The new age of MOFs and of their porous-related solids, Chemical Society Reviews, vol.46, issue.11, pp.3104-3107, 2017.
DOI : 10.1039/C7CS90049J

S. Kaskel, The Chemistry of Metal?Organic Frameworks: Synthesis, Characterization, and Applications, 2016.
DOI : 10.1002/9783527693078

H. Assi, G. Mouchaham, N. Steunou, T. Devic, and C. Serre, Titanium coordination compounds: from discrete metal complexes to metal???organic frameworks, Chemical Society Reviews, vol.137, issue.11, pp.3431-3452, 2017.
DOI : 10.1039/a706020c

URL : https://hal.archives-ouvertes.fr/hal-01721024

C. Serre, ???-Piperazinebismethylenephosphonates of Aluminum and Titanium, Chemistry of Materials, vol.18, issue.6, pp.1451-1457, 2006.
DOI : 10.1021/cm052149l

|. Doi, 10.1038/s41467-018-04034-w ARTICLE, NATURE COMMUNICATIONS NATURE COMMUNICATIONS |, vol.9, 2018.
URL : https://hal.archives-ouvertes.fr/in2p3-00652853

M. Dan-hardi, A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate, Journal of the American Chemical Society, vol.131, issue.31, pp.10857-10859, 2009.
DOI : 10.1021/ja903726m

URL : https://hal.archives-ouvertes.fr/hal-00474847

J. A. Mason, L. E. Darago, W. W. Lukens, . Jr, and J. Long, Reactivity of a Titanium(III) Metal???Organic Framework, Inorganic Chemistry, vol.54, issue.20, pp.10096-10104, 2015.
DOI : 10.1021/acs.inorgchem.5b02046

S. Yuan, A single crystalline porphyrinic titanium metal???organic framework, Chemical Science, vol.135, issue.7, pp.3926-3930, 2015.
DOI : 10.1021/ja408084j

URL : http://pubs.rsc.org/en/content/articlepdf/2015/sc/c5sc00916b

N. T. Nguyen, Three-Dimensional Metal-Catecholate Frameworks and Their Ultrahigh Proton Conductivity, Journal of the American Chemical Society, vol.137, issue.49, pp.15394-15397, 2015.
DOI : 10.1021/jacs.5b10999

H. Assi, Investigating the Case of Titanium(IV) Carboxyphenolate Photoactive Coordination Polymers, Inorganic Chemistry, vol.55, issue.15, pp.7192-7199, 2016.
DOI : 10.1021/acs.inorgchem.6b01060

B. Bueken, ] Cluster, Angewandte Chemie International Edition, vol.59, issue.47, pp.13912-13917, 2015.
DOI : 10.1103/PhysRevB.59.1758

H. L. Nguyen, The chemistry of titanium-based metal???organic frameworks, New Journal of Chemistry, vol.17, issue.23, pp.14030-14043, 2017.
DOI : 10.1021/acs.cgd.6b01597

H. L. Nguyen, A Titanium???Organic Framework as an Exemplar of Combining the Chemistry of Metal??? and Covalent???Organic Frameworks, Journal of the American Chemical Society, vol.138, issue.13, pp.4330-4333, 2016.
DOI : 10.1021/jacs.6b01233

L. Rozes, N. Steunou, G. Fornasieri, and C. Sanchez, Titanium-Oxo Clusters, Versatile Nanobuilding Blocks for the Design of Advanced Hybrid Materials, Monatshefte f??r Chemie - Chemical Monthly, vol.15, issue.5, pp.501-528, 2006.
DOI : 10.1557/PROC-435-137

URL : https://hal.archives-ouvertes.fr/hal-00107469

N. Steunou, F. Robert, K. Boubekeur, F. Ribot, and C. Sanchez, Synthesis through an in situ esterification process and characterization of oxo isopropoxo titanium clusters, Inorganica Chimica Acta, vol.279, issue.2, pp.144-151, 1998.
DOI : 10.1016/S0020-1693(98)00109-1

V. G. Ponomareva, Imparting High Proton Conductivity to a Metal???Organic Framework Material by Controlled Acid Impregnation, Journal of the American Chemical Society, vol.134, issue.38, pp.15640-15643, 2012.
DOI : 10.1021/ja305587n

G. Mouchaham, A Robust Infinite Zirconium Phenolate Building Unit to Enhance the Chemical Stability of Zr MOFs, Angewandte Chemie International Edition, vol.54, issue.45, pp.13297-13301, 2015.
DOI : 10.1021/ic502639v

URL : https://hal.archives-ouvertes.fr/hal-01416642

T. Zheng, Overcoming the crystallization and designability issues in the ultrastable zirconium phosphonate framework system, Nature Communications, vol.13, p.15369, 2017.
DOI : 10.1002/jcc.540130805

URL : http://www.nature.com/articles/ncomms15369.pdf

J. E. Mondloch, Vapor-Phase Metalation by Atomic Layer Deposition in a Metal???Organic Framework, Journal of the American Chemical Society, vol.135, issue.28, pp.10294-10297, 2013.
DOI : 10.1021/ja4050828

J. Jiang, Superacidity in Sulfated Metal???Organic Framework-808, Journal of the American Chemical Society, vol.136, issue.37, pp.12844-12847, 2014.
DOI : 10.1021/ja507119n

P. Deria, W. Bury, J. T. Hupp, and O. K. Farha, Versatile functionalization of the NU-1000 platform by solvent-assisted ligand incorporation, Chemical Communications, vol.23, issue.16, pp.1965-1968, 2014.
DOI : 10.1021/cm1022882

Y. Matsumoto, Room-Temperature Ferromagnetism in Transparent Transition Metal-Doped Titanium Dioxide, Science, vol.291, issue.5505, pp.854-856, 2001.
DOI : 10.1126/science.1056186

R. Asahi, T. Morikawa, H. Irie, and T. Ohwaki, Nitrogen-Doped Titanium Dioxide as Visible-Light-Sensitive Photocatalyst: Designs, Developments, and Prospects, Chemical Reviews, vol.114, issue.19, pp.9824-9852, 2014.
DOI : 10.1021/cr5000738

C. Wang, C. Liu, X. He, and Z. M. Sun, A cluster-based mesoporous Ti-MOF with sodalite supercages, Chem. Commun., vol.51, issue.85, pp.11670-11673, 2017.
DOI : 10.1021/ic301385u

W. H. Fang, L. Zhang, and J. Zhang, ???Oxo Nanocluster with Precise Atomic Structure, Journal of the American Chemical Society, vol.138, issue.24, pp.7480-7483, 2016.
DOI : 10.1021/jacs.6b03489

C. Liu and S. Yang, Synthesis of Angstrom-Scale Anatase Titania Atomic Wires, ACS Nano, vol.3, issue.4, pp.1025-1031, 2009.
DOI : 10.1021/nn900157r

H. Li, M. Eddaoudi, T. L. Groy, and O. M. Yaghi, Establishing Microporosity in Open Metal???Organic Frameworks:?? Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate), Journal of the American Chemical Society, vol.120, issue.33, pp.8571-8572, 1998.
DOI : 10.1021/ja981669x

C. G. Carson, Synthesis and Structure Characterization of Copper Terephthalate Metal-Organic Frameworks, European Journal of Inorganic Chemistry, vol.57, issue.16, pp.2338-2343, 2009.
DOI : 10.1002/cjoc.20030211014

K. C. Stylianou, Dimensionality Transformation through Paddlewheel Reconfiguration in a Flexible and Porous Zn-Based Metal???Organic Framework, Journal of the American Chemical Society, vol.134, issue.50, pp.20466-20478, 2012.
DOI : 10.1021/ja308995t

D. O. Scanlon, Band alignment of rutile and anatase TiO2, Nature Materials, vol.19, issue.9, pp.798-801, 2013.
DOI : 10.1116/1.571130

X. Wang, Z. Li, J. Shi, and Y. Yu, One-Dimensional Titanium Dioxide Nanomaterials: Nanowires, Nanorods, and Nanobelts, Chemical Reviews, vol.114, issue.19, pp.9346-9384, 2014.
DOI : 10.1021/cr400633s

C. H. Hendon, Engineering the Optical Response of the Titanium-MIL-125 Metal???Organic Framework through Ligand Functionalization, Journal of the American Chemical Society, vol.135, issue.30, pp.10942-10945, 2013.
DOI : 10.1021/ja405350u

URL : https://hal.archives-ouvertes.fr/hal-01289777

A. Saeki, S. Seki, T. Sunagawa, K. Ushida, and S. Tagawa, Charge-carrier dynamics in polythiophene films studied by in-situ measurement of flash-photolysis time-resolved microwave conductivity (FP-TRMC) and transient optical spectroscopy (TOS), Philosophical Magazine, vol.310, issue.9, pp.1261-1276, 2006.
DOI : 10.1103/PhysRevB.71.155204

S. Nakajima and R. Katoh, photocatalysts, Journal of Materials Chemistry A, vol.118, issue.30, pp.15466-15472, 2015.
DOI : 10.1021/jp502912u

A. Mohammadpour, S. Farsinezhad, B. D. Wiltshire, and K. Shankar, Majority carrier transport in single crystal rutile nanowire arrays, physica status solidi (RRL) - Rapid Research Letters, vol.106, issue.45, pp.512-516, 2014.
DOI : 10.1021/jp025844e

A. A. Talin, Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices, Science, vol.343, issue.6166, pp.66-69, 2014.
DOI : 10.1007/BF02886278

L. Sun, M. G. Campbell, and M. Dinca, Electrically Conductive Porous Metal-Organic Frameworks, Angewandte Chemie International Edition, vol.6, issue.11, pp.3566-3579, 2016.
DOI : 10.1021/am507016r

S. Han, Tunneling Electrical Connection to the Interior of Metal???Organic Frameworks, Journal of the American Chemical Society, vol.137, issue.25, pp.8169-8175, 2015.
DOI : 10.1021/jacs.5b03263

C. F. Leong, P. M. Usov, and D. M. D-'alessandro, Abstract, MRS Bulletin, vol.41, issue.11, pp.858-864, 2016.
DOI : 10.1557/mrs.2016.241

M. Dinca and F. Leonard, Abstract, MRS Bulletin, vol.343, issue.11, pp.854-857, 2016.
DOI : 10.1039/b008034i

J. Liu, Photoinduced Charge-Carrier Generation in Epitaxial MOF Thin Films: High Efficiency as a Result of an Indirect Electronic Band Gap?, Angewandte Chemie International Edition, vol.101, issue.25, pp.7441-7445, 2015.
DOI : 10.1063/1.4751286

Z. L. Wu, A Semi-Conductive Copper-Organic Framework with Two Types of Photocatalytic Activity, Angewandte Chemie International Edition, vol.14, issue.16, pp.4938-4942, 2016.
DOI : 10.1021/cg4014416

Y. Chang, W. Su, and L. Wang, Photoactive Polythiophene:Titania Hybrids with Excellent Miscibility for Use in Polymer Photovoltaic Cells, Macromolecular Rapid Communications, vol.18, issue.15, pp.1303-1308, 2008.
DOI : 10.1002/marc.200800134

T. Uemura, N. Yanai, and S. Kitagawa, Polymerization reactions in porous coordination polymers, Chemical Society Reviews, vol.130, issue.5, pp.1228-1236, 2009.
DOI : 10.1007/b107180

M. W. Maclean, Unraveling Inter- and Intrachain Electronics in Polythiophene Assemblies Mediated by Coordination Nanospaces, Angewandte Chemie International Edition, vol.48, issue.2, pp.708-713, 2016.
DOI : 10.1002/actp.1997.010480905

C. Lu, T. Ben, S. Xu, and S. Qiu, Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal-Organic Framework Thin Film, Angewandte Chemie International Edition, vol.18, issue.25, pp.6454-6458, 2014.
DOI : 10.1002/adma.200600445

T. Devic, C. Serre, N. Audebrand, J. Marrot, and G. Ferey, MIL-103, A 3-D Lanthanide-Based Metal Organic Framework with Large One-Dimensional Tunnels and A High Surface Area, Journal of the American Chemical Society, vol.127, issue.37, pp.12788-12789, 2005.
DOI : 10.1021/ja053992n

URL : https://hal.archives-ouvertes.fr/hal-00022688

E. Palomares, J. N. Clifford, S. A. Haque, T. Lutz, and J. Durrant, Control of Charge Recombination Dynamics in Dye Sensitized Solar Cells by the Use of Conformally Deposited Metal Oxide Blocking Layers, Journal of the American Chemical Society, vol.125, issue.2, pp.475-482, 2003.
DOI : 10.1021/ja027945w